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KMID : 1059519970410090502
Journal of the Korean Chemical Society
1997 Volume.41 No. 9 p.502 ~ p.517
Dehydropolymerization of Silanes to Polysilanes Catalyzed by Organometallic Complexes
Woo Hee-Gweon

Song Sun-Jung
Abstract
This review deals with (1) the catalytic systems and mechanisms for the dehydropolymerization of silanes to polysilanes, (2) the dehydropolymerization of versatile silanes, (3) the preparation of polysilane derivatives, and (4) the applications of catalytic dehydropolymerizing systems to ceramics. The efforts to maximize the catalytic efficiency of group 4 metallocenes were introduced. Finally, the future of this dehydropolymerizing techniques of silanes was foreseen.
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