KMID : 1059519970410090502
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Journal of the Korean Chemical Society 1997 Volume.41 No. 9 p.502 ~ p.517
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Dehydropolymerization of Silanes to Polysilanes Catalyzed by Organometallic Complexes
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Woo Hee-Gweon
Song Sun-Jung
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Abstract
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This review deals with (1) the catalytic systems and mechanisms for the dehydropolymerization of silanes to polysilanes, (2) the dehydropolymerization of versatile silanes, (3) the preparation of polysilane derivatives, and (4) the applications of catalytic dehydropolymerizing systems to ceramics. The efforts to maximize the catalytic efficiency of group 4 metallocenes were introduced. Finally, the future of this dehydropolymerizing techniques of silanes was foreseen.
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